This is a list of places where I think you can get good quality coffee in Aberystwyth. It's all just my opinion so please explore and feel free to suggest new venues.
35 Pier Street (at Marine Terrace), アベリストウィス, Ceredigion
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Simon M: The Olive Branch may not be a café but the proprietors are happy to serve just coffee when they're not busy. Why not find a window seat & try the really strong Greek coffee. That'll wake you up!